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Plant Diversity ›› 2013, Vol. 35 ›› Issue (4): 501-504.DOI: 10.7677/ynzwyj201313011

• 研究论文 • 上一篇    下一篇

菊状千里光中Jacaranone类化合物

 张丰, 苏日娜, 武海波, 王文蜀   

  1. 中央民族大学 生命与环境科学学院,北京100081
  • 收稿日期:2013-01-28 出版日期:2013-07-25 发布日期:2013-03-08
  • 基金资助:

    国家自然科学基金 (31200260);中央民族大学“111引智工程”项目 (B08044);中央民族大学“985”工程项目 (MUC98504-14、MUC98507-08) ;北京市教育委员会科技成果转化与产业化项目

Jacaranone Derivatives from Senecio laetus (Compositae)

 ZHANG  Feng, SU  Ri-Na, WU  Hai-Bo, WANG  Wen-Shu   

  1. College of Life and Environmental Sciences, Minzu University of China, Beijing 100081, China
  • Received:2013-01-28 Online:2013-07-25 Published:2013-03-08

摘要:

从菊状千里光(Senecio laetus)全草中分离得到7个Jacaranone类化合物,它们的结构运用现代波谱技术确定为jacaranone(1);3hydroxy2, 3dihydrojacaranone methyl ester(2);1-羟基-4-氧代-2, 5-环己二烯-1-醋酸乙酯(3);2jacaranone酰基-α-D-吡喃葡萄糖酯和2-jacaranone酰基-β-D-吡喃葡萄糖酯的混合物(4、5);l-jacaranone乙酯-β-D-吡喃葡萄糖苷(6);1-羟基-4-氧代-2, 5-环己二烯-1-醋酸(7)。首次报道菊状千里光中Jacaranone类化合物的存在,支持了国外学者认为该类化合物是千里光属植物特征次生代谢产物的推论。

关键词: 千里光属, 菊状千里光, Jacaranone

Abstract:

Seven jacaranone derivatives were isolated from the MeOH extract of the whole plants of Senecio laetus. Structures of the compounds were elucidated on the basis of extensive spectroscopic. They were jacaranone(1); 3hydroxy-2, 3dihydrojacaranone methyl ester(2); 1-hydroxy-4-oxo-2, 5-hex edine-1-ethyl acetate(3); the mixture of 2-jacaranoneacyl-α-D-pyran glucose ester and 2-jacaranoneacyl-β-D-pyran glucose ester(4, 5); l-jacaranonacetate-β-D-pyran glucose ester(6)and 1-hydroxy-4-oxo-2, 5-hexedine-1-ethylic acid(7). The jacaranone derivatives were all isolated from this plant for the first time. The results supported that jacaranone derivatives could be characteristic secondary metabolite of Senecio.

Key words: Senecio, Senecio laetus, Jacaranone

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