Plant Diversity ›› 1991, Vol. 13 ›› Issue (02): 1-3.

• Articles •    

A NOVEL C21 STEROIDAL GLYCOSIDE FROM MARSDENIA INCISA

HEN Ji-Jun,ZHANG Zhuang-Xin,ZHOU Jun,WANG De-Zu,ZHOU Lin,TAO Guo-Da   

  1. Laboratory of Phytochemistry,Kunming Institute of Botany,Academia Sinica, Kunming
  • Online:1991-04-25 Published:1991-04-25

Abstract: Besides a series of normal C21 steroids from Marsdenia incisa incisa P. T. Li et Y.P.Li,a small amount of novel C21 steroidal glycoside(II) had been isolated. The mild acidic hydrolysis of (II) afforded genin-(I).By spectroscopic analyses of IR,EIMS,FDMS,1H NMR,13C NMR (DEPT, PRFT),1H-1H COSY,1H-13CCOSY  for(I)and(II),(I)had been deduced as B-nor(7)-6β-formyl-pregnane-3β,5β,8β,12β,14β, 17β,20-heptatol,named neomarinogenin;(II)had been deduced as neomarinogenin 3-O- β-D-thevetopyranosyl- (1→4)- β-D- cymaropyranosyl-(1→4)-β-D-cymaropyranoside,named neomarinoside.Their physical and spectral data were as follows.

Key words: Novel C21 steroidal glycoside